A new X-ray technique developed by Cornell engineers has revealed the cause of a long-identified flaw in sodium-ion batteries; a discovery that could prove to be a major step toward making sodium-ion as ubiquitous as lithium-ion. Contact online >>
A new X-ray technique developed by Cornell engineers has revealed the cause of a long-identified flaw in sodium-ion batteries; a discovery that could prove to be a major step toward making sodium-ion as ubiquitous as lithium-ion.
Due to the wide availability and low cost of sodium resources, sodium-ion batteries (SIBs) are regarded as a promising alternative for next-generation large-scale EES systems. This review discusses in detail the key differences between lithium-ion batteries (LIBs) and SIBs for different application requirements and describes the current
This chapter addresses those processes occurring in Na-ion battery systems, which relate to a reduction in cell performance as components age, degrade or fail over time and/or cycling. It discusses the aspects of degradation relating for the most part to a hard carbon anode and a layered oxide cathode. The chapter discusses different aspects
Researchers used transmission electron microscopy (left) and X-ray techniques (right) to observe the defects that led to failure in sodium-ion battery cathodes. Eliminating these defects will allow these batteries to last longer.
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a Advantages and limitations of ABSs. b Novel strategies for each part of the cathode, anode, and electrolytes, which are major components of ABSs. c Radar plots of characteristics of each system (Li, Zn, Na, Ma, Al).
Overall, the development of aqueous batteries has been driven by the commercial success of Li-ion organic electrolyte systems in the battery industry. The first aqueous Li-ion battery (ALIB) was proposed in 1994 using a conventional spinel cathode (LMO), which had a relatively low operating voltage of 1.5 V and an energy density of ~55 Wh kg−1, larger than Pb-acid batteries. However, it had poor cycle life, lasting only approximately 25 cycles. The conventional cathode structure is shown in Fig. 3a.
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